List of Publications by Department for the Academic Year Biochar derived from citronella and oregano waste residues for removal of organic dyes and soil amendment
Abstract
The exponential growth and prominence of the essential oil industry was associated with the generation of large
amounts of plant residues which, if not managed properly, present an environmental threat due to their ability to
contaminate soil and water systems. This study focuses on the valorization of residues generated from oregano
and citronella plants following essential oil extraction. To tackle this challenge, we investigated the potential of
biochar of oregano and citronella residues for removing methyl orange dye, a common environmental pollutant,
and assessed their phytotoxicity for potential applications as soil amendment. The biochar was produced at
different pyrolysis temperatures (300 ◦C and 400 ◦C) to study the effect of temperature on the various physicochemical
properties of the biochar. Several analytical techniques were used to characterize the generated
biochar including Fourier Transform infrared (FTIR) spectroscopy, Scanning Electron Microscopy (SEM), X-ray
energy dispersive (EDX) spectroscopy, and X-ray diffraction (XRD) spectroscopy. The efficiency of oregano and
citronella biochars produced at different temperatures as soil amendment was evaluated by examining the
germination and root development of Lepidium sativum seeds commonly known as garden cress. The control
group displayed strong performance with 90–100 % germination and 3.54 cm root length. Oregano biochar
obtained by pyrolysis at 300 ◦C (BOR-300) was toxic to seed growth, while the biochar fabricated at 400 ◦C
(BOR-400) improved germination but fell short of the control. On the other hand, citronella biochar generated at
300 ◦C (BCR-300) and 400 ◦C (BCR-400) resulted in better germination compared to BOR, but still lagged behind
the control group. Furthermore, our results demonstrated that citronella biochar (BCR) at 400 ◦C effectively
removed 88.8 % of the methyl orange dye. Conversely, the combination of oregano biochar (BOR) and citronella
biochar (BCR) at 300 ◦C did not substantially affect the dye removal efficiency. In summary, applying BOR and
BCR produced at 400 ◦C to soil appears environmentally safe but does not significantly enhance plant growth.
These results highlight the critical roles played by biochar type and pyrolysis temperature in shaping the
application process.
Journal/Conference Information
Current Research in Green and Sustainable Chemistry,DOI: https://doi.org/10.1016/j.crgsc.2024.100433, ISSN: 2666-0865, Volume: 9, Issue: NA, Pages Range: 1-11,